Reconfigurable All-Nitride Magneto-Ionics.

Journal: ACS nano
Published Date:

Abstract

The rapid advancement of generative artificial intelligence has significantly increased the demand for both energy and data storage. Magneto-ionics, which utilizes ionic motion to control magnetism, often driven by an electric field in heterostructures, has gained significant attention for its potential to enable energy-efficient modulation of magnetic properties with large effects. This study proposes a CMOS-compatible solid-state magneto-ionic system composed of all-Mn-nitrides and demonstrates that nitrogen ionic motion can induce reversible phase transitions between ferrimagnetic and antiferromagnetic Mn nitrides. This magnetic phase transition is manifested in dramatic changes in the resultant exchange bias effect, which can be increased by over an order of magnitude when more nitrogen is introduced into the nitrides during deposition and subsequently reduced by over 70% when nitrogen is taken out of the nitrides through post-annealing. Additionally, voltage-induced nitrogen ionic motion can lead to reversible changes in saturation magnetization and the exchange bias effect by 23% and 0.1 T (16%) at 5 K, respectively. These findings highlight the characteristics of this all-Mn-nitride system as an industrially viable and environmentally sustainable platform, offering tunable magnetic properties and energy-efficient operation and potential for magnetic field immunity.

Authors

  • Zhijie Chen
    Physics Department, Georgetown University, Washington, District of Columbia 20057, United States.
  • Christopher J Jensen
    Physics Department, Georgetown University, Washington, District of Columbia 20057, United States.
  • Chen Liu
    Department of Radiology, Southwest Hospital, Third Military Medical University (Army Military Medical University), Chongqing, China.
  • Yijing Liu
    College of Computer Science, Sichuan University Chengdu 610064 People's Republic of China.
  • Christy J Kinane
    ISIS Neutron Facility, STFC Rutherford Appleton Laboratory, Chilton OX11 0QX, Oxfordshire, U.K.
  • Andrew John Caruana
    ISIS Neutron Facility, STFC Rutherford Appleton Laboratory, Chilton OX11 0QX, Oxfordshire, U.K.
  • Alexander J Grutter
    NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, United States.
  • Julie A Borchers
    NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, United States.
  • Xixiang Zhang
    King Abdullah University of Science & Technology, Thuwal 23955-6900, Saudi Arabia.
  • Kai Liu
    College of Marine Sciences, Shanghai Ocean University, Shanghai 201306, China.

Keywords

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