Pnictogen-functionalised isocyanide ligands.

Journal: Dalton transactions (Cambridge, England : 2003)
Published Date: May 12, 2025

Abstract

The reactions of a range of cyanometallate salts with ClABu (A = P, As, Sb, A ≠ Bi) afford the new phosphino, arsino and stibino-isonitrile complexes [M(CNABu)(CO)] (M = W, A = P, As, Sb) and [ML(CNPBu)] [ML = Cr(CO), Mo(CO), Mn(CO)(η-CH), Re(CO)(η-CH), Fe(CO), Fe(CO)(PPh)] allowing crystallographic spectroscopic and computational interrogation of isonitrile compexes functionalised by the heavier pnictogens.

Authors

  • Ryan M Kirk
    Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory, ACT 2601, Australia. a.hill@anu.edu.au.
  • Anthony F Hill
    Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory, ACT 2601, Australia. a.hill@anu.edu.au.

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