Estimating Absolute Protein-Protein Binding Free Energies by a Super Learner Model.

Journal: Journal of chemical information and modeling
Published Date:

Abstract

Protein-protein binding is central to most biochemical processes of all living beings. Its importance underlies mechanisms ranging from cell interactions to metabolic control, but also to biotechnology, such as the development of therapeutic monoclonal antibodies, the engineering of enzymes for industrial biocatalysis, the development of biosensors for disease detection, and the assembly of artificial protein complexes for drug screening. Therefore, predicting the strength of their association allows for understanding the molecular mechanisms and ultimately controlling them. We devised a machine learning ensemble model that uses Rosetta-based quantities to predict binding free energies of protein-protein complexes with accuracy rivaling both computationally demanding methods and currently available ML/DL tools. The method was encoded into an application Python pipeline named PBEE, which stands for Protein Binding Energy Estimator, allowing a rapid calculation of the absolute binding free energies of protein complexes from their PDB coordinates.

Authors

  • Elton J F Chaves
    Aggeu Magalhães Institute, Oswaldo Cruz Foundation, Recife 50670-465, Brazil.
  • João Sartori
    Laboratory for Applied Genomics and Bio-Innovations, Oswaldo Cruz Foundation, Rio de Janeiro 21040-900, Brazil.
  • Whendel M Santos
    Department of Fundamental Chemistry, Federal University of Pernambuco, Recife 50670-901, Brazil.
  • Carlos H B Cruz
    Institute of Structural and Molecular Biology, University College London, London WC1E 6BT, U.K.
  • Emmanuel N Mhrous
    Department of Computer Science, Princeton University, Princeton, New Jersey 08544, United States.
  • Manassés F Nacimento-Filho
    Institute of Structural and Molecular Biology, University College London, London WC1E 6BT, U.K.
  • Matheus V F Ferraz
    Department of Virology, Aggeu Magalhães Institute, Oswaldo Cruz Foundation, FIOCRUZ, Recife, PE, Brazil.
  • Roberto D Lins
    Department of Virology, Aggeu Magalhães Institute, Oswaldo Cruz Foundation, FIOCRUZ, Recife, PE, Brazil.