Machine learning-driven prediction of phosphorus removal performance of metal-modified biochar and optimization of preparation processes considering water quality management objectives.

Journal: Bioresource technology
PMID:

Abstract

Developing an optimized and targeted design approach for metal-modified biochar based on water quality conditions and management is achievable through machine learning. This study leveraged machine learning to analyze experimental data on phosphate adsorption by metal-modified biochar from literature published in Web of Science. Using six machine learning models, the phosphate adsorption capacity of biochar and residual phosphate concentration were predicted. After hyperparameter optimization, the gradient boosting model exhibited superior training performance (R > 0.96). Metal load quantity, solid-liquid ratio, and pH were key factors influencing adsorption performance. Optimal preparation parameters indicated that Mg-modified biochar achieved the highest adsorption capacity (387-396 mg/g), while La-modified biochar displayed the lowest residual phosphate concentration (0 mg/L). The results of verification experiments based on optimized process parameters closely aligned with model predictions. This study introduces a new machine learning-based approach for tailoring biochar preparation processes considering different water quality management objectives.

Authors

  • Weilin Fu
    Pattern Recognition Lab, Friedrich-Alexander-Universität Erlangen-Nürnberg, Erlangen, Germany. weilin.fu@fau.de.
  • Menghan Feng
    Agro-Environmental Protection Institute, Ministry of Agriculture and Rural Affairs, Tianjin 300191, China; Dali Comprehensive Experimental Station of Environmental Protection Research and Monitoring Institute, Ministry of Agriculture and Rural Affairs (Dali Original Seed Farm), Dali 671004, China.
  • Changbin Guo
    Agro-Environmental Protection Institute, Ministry of Agriculture and Rural Affairs, Tianjin 300191, China; Dali Comprehensive Experimental Station of Environmental Protection Research and Monitoring Institute, Ministry of Agriculture and Rural Affairs (Dali Original Seed Farm), Dali 671004, China.
  • Jien Zhou
    Agro-Environmental Protection Institute, Ministry of Agriculture and Rural Affairs, Tianjin 300191, China; Dali Comprehensive Experimental Station of Environmental Protection Research and Monitoring Institute, Ministry of Agriculture and Rural Affairs (Dali Original Seed Farm), Dali 671004, China.
  • Xueyan Zhang
    National Institute of Occupational Health and Poison Control, Chinese Center for Disease Control and Prevention, Beijing 100050, China.
  • Shiyu Lv
    Agro-Environmental Protection Institute, Ministry of Agriculture and Rural Affairs, Tianjin 300191, China; Dali Comprehensive Experimental Station of Environmental Protection Research and Monitoring Institute, Ministry of Agriculture and Rural Affairs (Dali Original Seed Farm), Dali 671004, China.
  • Yingqiu Huo
    College of Information Engineering, Northwest A&F University, Yangling, Shaanxi 712100, China. Electronic address: fallying@nwsuaf.edu.cn.
  • Feng Wang
    Department of Oncology, Binzhou Medical University Hospital, Binzhou, Shandong, China.