Rapid evaluation of Curcuma origin and quality based on E-eye, flash GC e-nose, and FT-NIR combined with machine learning technologies.

Journal: Food chemistry
Published Date:

Abstract

Curcuma, a key ingredient in curry and a popular health supplement, has been subject to adulteration and fraudulent origin labeling. In this study, E-eye, Flash GC e-nose, and FT-NIR, combined with machine learning and multivariate algorithms, were employed for origin identification and quantitative prediction of curcuma constituents. The results indicated that E-eye performed poorly in origin classification, while Flash GC e-nose identified flavor markers distinguishing curcuma from different origins but lacked precise quantification. After processing the FT-NIR spectra with SNV, the accuracy of three machine learning models, including SVM, increased from 83.3 % to 100 %. Additionally, PLSR models for three constituents, including curcumin, achieved mean R values exceeding 0.99 in both training and prediction sets, demonstrating excellent linearity and predictive accuracy. Overall, the study demonstrated that FT-NIR combined with multivariate algorithms provides an effective and feasible method for rapid origin identification and quality assessment of curcuma.

Authors

  • Qiang Guo
  • Ming-Xuan Li
    College of Pharmacy, Nanjing University of Chinese Medicine, Nanjing 210023, China.
  • Rao Fu
    Department of Ultrasound, The People's Hospital of Anyang city, Anyang, China.
  • Xin Wan
    SCNU Environmental Research Institute, Guangdong Provincial Key Laboratory of Chemical Pollution and Environmental Safety & MOE Key Laboratory of Theoretical Chemistry of Environment, School of Environment, South China Normal University, Guangzhou, 510006, PR China; SCNU Qingyuan Institute of Science and Technology Innovation Co, Ltd, Qingyuan 511517, PR China.
  • Wen-Hao Dong
    College of Pharmacy, Nanjing University of Chinese Medicine, Nanjing 210023, China.
  • Chun-Qin Mao
    College of Pharmacy, Nanjing University of Chinese Medicine, Nanjing 210023, China.
  • Zhen-Hua Bian
    College of Pharmacy, Nanjing University of Chinese Medicine, Nanjing 210023, China; Department of Pharmacy, Wuxi TCM Hospital Affiliated to Nanjing University of Chinese Medicine, Wuxi 214071, China. Electronic address: 20193096@njucm.edu.cn.
  • De Ji
    College of Pharmacy, Nanjing University of Chinese Medicine, Nanjing, PR China.
  • Tu-Lin Lu
    College of Pharmacy, Nanjing University of Chinese Medicine, Nanjing 210023, China. Electronic address: ltl2021@njucm.edu.cn.
  • Yu Li
    Department of Public Health, Shihezi University School of Medicine, 832000, China.