A Deep Learning Approach to Organic Pollutants Classification Using Voltammetry.

Journal: Sensors (Basel, Switzerland)
Published Date:

Abstract

This paper proposes a deep leaning technique for accurate detection and reliable classification of organic pollutants in water. The pollutants are detected by means of cyclic voltammetry characterizations made by using low-cost disposable screen-printed electrodes. The paper demonstrates the possibility of strongly improving the detection of such platforms by modifying them with nanomaterials. The classification is addressed by using a deep learning approach with convolutional neural networks. To this end, the results of the voltammetry analysis are transformed into equivalent RGB images by means of Gramian angular field transformations. The proposed technique is applied to the detection and classification of hydroquinone and benzoquinone, which are particularly challenging since these two pollutants have a similar electroactivity and thus the voltammetry curves exhibit overlapping peaks. The modification of electrodes by carbon nanotubes improves the sensitivity of a factor of about ×25, whereas the convolution neural network after Gramian transformation correctly classifies 100% of the experiments.

Authors

  • Mario Molinara
    Department of Electrical and Information Engineering "Maurizio Scarano", University of Cassino and Southern Lazio, 03043 Cassino (FR), Italy.
  • Rocco Cancelliere
    Department of Chemical Science and Technologies, University of Rome "Tor Vergata", 00133 Rome, Italy.
  • Alessio Di Tinno
    Department of Chemical Science and Technologies, University of Rome "Tor Vergata", 00133 Rome, Italy.
  • Luigi Ferrigno
    Department of Electrical and Information Engineering, University of Cassino and Southern Lazio, 03043 Cassino, Italy.
  • Mikhail Shuba
    Center of Physical Science and Technologies, 10257 Vilnius, Lithuania.
  • Polina Kuzhir
    Institute of Photonics, Department of Physics and Mathematics, University of Eastern Finland, 80101 Joensuu, Finland.
  • Antonio Maffucci
    Department of Electrical and Information Engineering, University of Cassino and Southern Lazio, 03043 Cassino, Italy.
  • Laura Micheli
    Department of Chemical Science and Technologies, University of Rome "Tor Vergata", 00133 Rome, Italy.