Combining physical mechanisms and deep learning models for hourly surface ozone retrieval in China.
Journal:
Journal of environmental management
Published Date:
Dec 26, 2023
Abstract
As surface ozone (O) gains increasing attention, there is an urgent need for high temporal resolution and accurate O monitoring. By taking advantage of the progress in artificial intelligence, deep learning models have been applied to satellite based O retrieval. However, the underlying physical mechanisms that influence surface O into model construction have rarely been considered. To overcome this issue, we considered the physical mechanisms influencing surface O and used them to select relevant variable features for developing a novel deep learning model. We used a wide and deep model architecture to account for linear and non-linear relationships between the variables and surface O. Using the developed model, we performed hourly inversions of surface O retrieval over China from 2017 to 2019 (9:00-17:00, local time). The validation results based on sample-based (site-based) methods yielded an R of 0.94 (0.86) and an RMSE of 12.79 (19.13) μg/m, indicating the accuracy of the models. The average surface O concentrations in China in 2017, 2018, and 2019 were 82, 78, and 87 μg/m, respectively. There was a diurnal pattern in surface O in China, with levels rising significantly from 55 μg/m at 9:00 a.m. to 96 μg/m at 15:00. Between 15:00 and 16:00, the O concentration remained stable at 95 μg/m and decreased slightly thereafter (16:00-17:00). The results of this study contribute to a deeper understanding of the physical mechanisms of ozone and facilitate further studies on ozone monitoring, thereby enhancing our understanding of the spatiotemporal characteristics of ozone.