Predictive analysis and risk assessment of potentially toxic elements in Beijing gas station soils using machine learning and two-dimensional Monte Carlo simulations.

Journal: Journal of hazardous materials
PMID:

Abstract

Gas stations not only serve as sites for oil storage and refueling but also as locations where vehicles frequently brake, significantly enriching the surrounding soil with potentially toxic elements (PTEs). Herein, 117 topsoil samples from gas stations were collected in Beijing to explore the impact of gas stations on PTE accumulation. The analysis revealed that the average Pollution Index (PI) values for Cd, Hg, Pb, Cu, and Zn in the soil samples all exceeded 1. The random forest (RF) model, achieving an AUC score of 0.95, was employed to predict PTE pollution at 372 unsampled gas stations. Additionally, a Positive Matrix Factorization (PMF) model indicated that gas station operations and vehicle emissions were responsible for 70 % of the lead (Pb) enrichment. Probabilistic health risk assessments showed that the carcinogenic risk (CR) and noncarcinogenic risk (NCR) for PTE pollution to adult females were the highest, at 0.451 and 1.61E-05 respectively, but still within acceptable levels. For adult males at contaminated sites, the Pb-associated CR and NCR were approximately twice as high as those at uncontaminated sites, with increases of 107 % and 81 %, respectively. This study provides new insights for managing pollution caused by gas stations.

Authors

  • Meiying Wang
    Department of Rheumatology and Immunology, Institute of Translational Medicine, Health Science Center, The First Affiliated Hospital of Shenzhen University, Shenzhen Second People's Hospital, Shenzhen, China.
  • Zilun Gou
    State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China.
  • Wenhao Zhao
    Department of Spine Surgery, The Affiliated Hospital of Qingdao University, Qingdao, China.
  • Yajing Qu
    State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China.
  • Ying Chen
    Department of Endocrinology and Metabolism, Fudan Institute of Metabolic Diseases, Zhongshan Hospital, Fudan University, Shanghai, China.
  • Yi Sun
    Department of Environmental and Occupational Health, Program in Public Health, University of California, Irvine, CA, USA.
  • Yuxuan Cai
    State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China.
  • Jin Ma
    State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China. Electronic address: majin@craes.org.cn.