SERS-ATB: A comprehensive database server for antibiotic SERS spectral visualization and deep-learning identification.

Journal: Environmental pollution (Barking, Essex : 1987)
PMID:

Abstract

The rapid and accurate identification of antibiotics in environmental samples is critical for addressing the growing concern of antibiotic pollution, particularly in water sources. Antibiotic contamination poses a significant risk to ecosystems and human health by contributing to the spread of antibiotic resistance. Surface-enhanced Raman spectroscopy (SERS), known for its high sensitivity and specificity, is a powerful tool for antibiotic identification. However, its broader application is constrained by the lack of a large-scale antibiotic spectral database crucial for environmental and clinical use. To address this need, we systematically collected 12,800 SERS spectra for 200 environmentally relevant antibiotics and developed an open-access, web-based database at http://sers.test.bniu.net/. We compared six machine learning algorithms with a convolutional neural network (CNN) model, which achieved the highest accuracy at 98.94%, making it the preferred database model. For external validation, CNN demonstrated an accuracy of 82.8%, underscoring its reliability and practicality for real-world applications. The SERS database and CNN prediction model represent a novel resource for environmental monitoring, offering significant advantages in terms of accessibility, speed, and scalability. This study establishes the large-scale, public SERS spectral databases for antibiotics, facilitating the integration of SERS into environmental programs, with the potential to improve antibiotic detection, pollution management, and resistance mitigation.

Authors

  • Quan Yuan
    School of Vehicle and Mobility, Tsinghua University, Beijing 100084, China.
  • Jia-Wei Tang
    Department of Intelligent Medical Engineering, School of Medical Informatics and Engineering, Xuzhou Medical University, Xuzhou, Jiangsu Province, China.
  • Jie Chen
    School of Basic Medical Sciences, Health Science Center, Ningbo University, Ningbo, China.
  • Yi-Wen Liao
    Laboratory Medicine, Guangdong Provincial People's Hospital (Guangdong Academy of Medical Sciences), Southern Medical University, Guangzhou, Guangdong Province, China.
  • Wen-Wen Zhang
    Department of Clinical Medicine, School of 1st Clinical Medicine, Xuzhou Medical University, Xuzhou, Jiangsu Province, China.
  • Xin-Ru Wen
    Laboratory Medicine, Guangdong Provincial People's Hospital (Guangdong Academy of Medical Sciences), Southern Medical University, Guangzhou, Guangdong Province 510080, China; School of Medical Informatics and Engineering, Xuzhou Medical University, Xuzhou, Jiangsu Province 210000, China.
  • Xin Liu
    Peking University Institute of Advanced Agricultural Sciences, Shandong Laboratory of Advanced Agricultural Sciences, Weifang, Shandong, China.
  • Hui-Jin Chen
    Guangzhou Institute of Cancer Research, The Affiliated Cancer Hospital, Guangzhou Medical University, Guangzhou, 510182, China.
  • Liang Wang
    Information Department, Dazhou Central Hospital, Dazhou 635000, China.