Raman spectroscopy combined with multiple one-dimensional deep learning models for simultaneous quantification of multiple components in blended olive oil.

Journal: Food chemistry
PMID:

Abstract

Blended vegetable oils are highly prized by consumers for their comprehensive nutritional profile. Therefore, there is an urgent need for a rapid and accurate method to identify the true content of blended oils. This study combined Raman spectroscopy with three deep learning models (CNN-LSTM, improved AlexNet, and ResNet) to simultaneously quantify extra virgin olive oil (EVOO), soybean oil, and sunflower oil in olive blended oil. The results demonstrate that all three deep learning models exhibited superior predictive ability compared to traditional chemometric methods. Specifically, the CNN-LSTM model achieved a coefficient of determination (Rp) of over 0.995 for each oil in the quantitative analysis of three-component blended oils, with a mean square error of prediction (RMSEP) of less than 2%. This study presents a novel approach for the simultaneous quantitative analysis of multi-component blended oils, providing a rapid and accurate method for the identification of falsely labeled blended oils.

Authors

  • Xijun Wu
    Measurement Technology & Instrumentation Key Laboratory of Hebei Province, Institute of Electrical Engineering, Yanshan University, Qinhuangdao 066004, China. Electronic address: wuxijun@ysu.edu.cn.
  • Xin Zhang
    First Department of Infectious Diseases, The First Affiliated Hospital of China Medical University, Shenyang, China.
  • Zherui Du
    Measurement Technology & Instrumentation Key Laboratory of Hebei Province, Institute of Electrical Engineering, Yanshan University, Qinhuangdao 066004, China.
  • Daolin Yang
    Measurement Technology & Instrumentation Key Laboratory of Hebei Province, Institute of Electrical Engineering, Yanshan University, Qinhuangdao 066004, China.
  • Baoran Xu
    Measurement Technology & Instrumentation Key Laboratory of Hebei Province, Institute of Electrical Engineering, Yanshan University, Qinhuangdao 066004, China.
  • Renqi Ma
    Measurement Technology & Instrumentation Key Laboratory of Hebei Province, Institute of Electrical Engineering, Yanshan University, Qinhuangdao 066004, China.
  • Hao Luo
    School of Public Health Sciences, University of Waterloo, Waterloo, ON, Canada.
  • Hailong Liu
    Measurement Technology & Instrumentation Key Laboratory of Hebei Province, Institute of Electrical Engineering, Yanshan University, Qinhuangdao 066004, China.
  • Yungang Zhang
    Measurement Technology & Instrumentation Key Laboratory of Hebei Province, Institute of Electrical Engineering, Yanshan University, Qinhuangdao 066004, China.