Application of parallel artificial membrane permeability assay technique and chemometric modeling for blood-brain barrier permeability prediction of protein kinase inhibitors.

Journal: Future medicinal chemistry
Published Date:

Abstract

This study aims to investigate the passive diffusion of protein kinase inhibitors through the blood-brain barrier (BBB) and to develop a model for their permeability prediction. We used the parallel artificial membrane permeability assay to obtain logPe values of each of 34 compounds and calculated descriptors for these structures to perform quantitative structure-property relationship modeling, creating different regression models. The logPe values have been calculated for all 34 compounds. Support vector machine regression was considered the most reliable, and CATS2D_09_DA, CATS2D_04_AA, B04[N-S] and F07[C-N] descriptors were identified as the most influential to passive BBB permeability. The quantitative structure-property relationship-support vector machine regression model that has been generated can serve as an efficient method for preliminary screening of BBB permeability of new analogs.

Authors

  • Milan Jovanovic
    Ada Health GmbH, Adalbertstraße 20, 10997, Berlin, Germany.
  • Milica Radan
    Institute for Medicinal Plant Research "Dr. Josif Pančić", Tadeuša Košćuška 1, Belgrade, 11000, Serbia.
  • Marija Čarapić
    Medicines & Medical Devices Agency of Serbia, Vojvode Stepe 458, 11000, Belgrade, Serbia.
  • Nenad Filipovic
  • Katarina Nikolic
    University of Belgrade - Faculty of Pharmacy, Department of Pharmaceutical Chemistry, Vojvode Stepe 450, P.O.Box 146, 11221, Belgrade, Serbia.
  • Milkica Crevar
    University of Belgrade - Faculty of Pharmacy, Department of Pharmaceutical Chemistry, Vojvode Stepe 450, P.O.Box 146, 11221, Belgrade, Serbia.