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Chemistry, Organic

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Expert system for predicting reaction conditions: the Michael reaction case.

Journal of chemical information and modeling
A generic chemical transformation may often be achieved under various synthetic conditions. However, for any specific reagents, only one or a few among the reported synthetic protocols may be successful. For example, Michael β-addition reactions may ...

Planning chemical syntheses with deep neural networks and symbolic AI.

Nature
To plan the syntheses of small organic molecules, chemists use retrosynthesis, a problem-solving technique in which target molecules are recursively transformed into increasingly simpler precursors. Computer-aided retrosynthesis would be a valuable t...

Computational planning of the synthesis of complex natural products.

Nature
Training algorithms to computationally plan multistep organic syntheses has been a challenge for more than 50 years. However, the field has progressed greatly since the development of early programs such as LHASA, for which reaction choices at each s...

Valid, Plausible, and Diverse Retrosynthesis Using Tied Two-Way Transformers with Latent Variables.

Journal of chemical information and modeling
Retrosynthesis is an essential task in organic chemistry for identifying the synthesis pathways of newly discovered materials, and with the recent advances in deep learning, there have been growing attempts to solve the retrosynthesis problem through...

Augmenting Adaptive Machine Learning with Kinetic Modeling for Reaction Optimization.

The Journal of organic chemistry
We combine random sampling and active machine learning (ML) to optimize the synthesis of isomacroin, executing only 3% of all possible Friedländer reactions. Employing kinetic modeling, we augment machine intuition by extracting mechanistic knowledge...

Machine-Learning-Guided Discovery of Electrochemical Reactions.

Journal of the American Chemical Society
The molecular structures synthesizable by organic chemists dictate the molecular functions they can create. The invention and development of chemical reactions are thus critical for chemists to access new and desirable functional molecules in all dis...

Quantitative Prediction of Inorganic Nanomaterial Cellular Toxicity via Machine Learning.

Small (Weinheim an der Bergstrasse, Germany)
Organic chemistry has seen colossal progress due to machine learning (ML). However, the translation of artificial intelligence (AI) into materials science is challenging, where biological behavior prediction becomes even more complicated. Nanotoxicit...

CTsynther: Contrastive Transformer Model for End-to-End Retrosynthesis Prediction.

IEEE/ACM transactions on computational biology and bioinformatics
Retrosynthesis prediction is a fundamental problem in organic chemistry and drug synthesis. We proposed an end-to-end deep learning model called CTsynther (Contrastive Transformer for single-step retrosynthesis prediction model) that could provide si...