AIMC Topic: Thermodynamics

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Experimental Voltammetry Analyzed Using Artificial Intelligence: Thermodynamics and Kinetics of the Dissociation of Acetic Acid in Aqueous Solution.

Analytical chemistry
Artificial intelligence (AI) is used to quantitatively analyze the voltammetry of the reduction of acetic acid in aqueous solution generating thermodynamic and kinetic data. Specifically, the variation of the steady-state current for the reduction of...

Harnessing Deep Learning for Optimization of Lennard-Jones Parameters for the Polarizable Classical Drude Oscillator Force Field.

Journal of chemical theory and computation
The outcomes of computational chemistry and biology research, including drug design, are significantly influenced by the underlying force field (FF) used in molecular simulations. While improved FF accuracy may be achieved via inclusion of explicit t...

Accurate Sampling of Macromolecular Conformations Using Adaptive Deep Learning and Coarse-Grained Representation.

Journal of chemical information and modeling
Conformational sampling of protein structures is essential for understanding biochemical functions and for predicting thermodynamic properties such as free energies. Where previous approaches rely on sequential sampling procedures, recent development...

Affinity prediction using deep learning based on SMILES input for D3R grand challenge 4.

Journal of computer-aided molecular design
Modern molecular docking comprises the prediction of pose and affinity. Prediction of docking poses is required for affinity prediction when three-dimensional coordinates of the ligand have not been provided. However, a large number of feature engine...

Extended DeepILST for Various Thermodynamic States and Applications in Coarse-Graining.

The journal of physical chemistry. A
Molecular dynamics (MD) simulations are widely used to obtain the microscopic properties of atomistic systems when the interatomic potential or the coarse-grained potential is known. In many practical situations, however, it is necessary to predict t...

GLOW: A Workflow Integrating Gaussian-Accelerated Molecular Dynamics and Deep Learning for Free Energy Profiling.

Journal of chemical theory and computation
We introduce a Gaussian-accelerated molecular dynamics (GaMD), deep learning (DL), and free energy profiling workflow (GLOW) to predict molecular determinants and map free energy landscapes of biomolecules. All-atom GaMD-enhanced sampling simulations...

TorsionNet: A Deep Neural Network to Rapidly Predict Small-Molecule Torsional Energy Profiles with the Accuracy of Quantum Mechanics.

Journal of chemical information and modeling
Fast and accurate assessment of small-molecule dihedral energetics is crucial for molecular design and optimization in medicinal chemistry. Yet, accurate prediction of torsion energy profiles remains challenging as the current molecular mechanics (MM...

Group Contribution and Machine Learning Approaches to Predict Abraham Solute Parameters, Solvation Free Energy, and Solvation Enthalpy.

Journal of chemical information and modeling
We present a group contribution method (SoluteGC) and a machine learning model (SoluteML) to predict the Abraham solute parameters, as well as a machine learning model (DirectML) to predict solvation free energy and enthalpy at 298 K. The proposed gr...

Pyrolytic characteristics of fine materials from municipal solid waste using TG-FTIR, Py-GC/MS, and deep learning approach: Kinetics, thermodynamics, and gaseous products distribution.

Chemosphere
Fine materials (FM) from municipal solid waste (MSW) classification require disposal, and pyrolysis is a feasible method for the treatments. Hence, the behavior, kinetics, and products of FM pyrolysis were investigated in this study. A deep learning ...

Molecular Energies Derived from Deep Learning: Application to the Prediction of Formation Enthalpies Up to High Energy Compounds.

Molecular informatics
Total electronic energies and frequencies predicted using the deep learning models ANI-1x and ANI-1ccx are converted to gas-phase formation enthalpies Δ H using an atom equivalent (AE) scheme for a database of CHNO compounds. As expected from the acc...