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Polymerization

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Magnetic nanoparticles coated with poly(p-phenylenediamine-co-thiophene) as a sorbent for preconcentration of organophosphorus pesticides.

Mikrochimica acta
The authors describe the preparation of FeO nanoparticles coated with poly(p-phenylenediamine-co-thiophene). The resulting nanoparticles (NPs) are shown to be viable sorbents for use in magnetic solid-phase extraction (MSPE) of organophosphorus pesti...

Betulin-loaded PEDOT films for regional chemotherapy.

Materials science & engineering. C, Materials for biological applications
Chemotherapy is one of the most commonly used cancer treatments. Even so, it has significant adverse effects on healthy tissues. These effects can be avoided through the use of regional chemotherapy, an approach based on delivering the anti-cancer ag...

Optimization and modelling of enzymatic polymerization of ε-caprolactone to polycaprolactone using Candida Antartica Lipase B with response surface methodology and artificial neural network.

Enzyme and microbial technology
Recently enzymatic catalysts have replaced organic and organometallic catalysts in the synthesis of bio-resorbable polymers. Enzymatic polymerization is considered as an alternative to conventional polymerization as they are less toxic, environmental...

Plasma-Induced Polymerizations: A New Synthetic Entry in Liquid Crystal Elastomer Actuators.

Macromolecular rapid communications
The research on soft actuators including liquid crystal elastomers (LCEs) becomes more and more appealing at a time when the expansion of artificial systems is blooming. Among the various LCE actuators, the bending deformation is often in the origin ...

Femtosecond laser programmed artificial musculoskeletal systems.

Nature communications
Natural musculoskeletal systems have been widely recognized as an advanced robotic model for designing robust yet flexible microbots. However, the development of artificial musculoskeletal systems at micro-nanoscale currently remains a big challenge,...

Morphological Fabrication of Equilibrium and Auditory Sensors through Electrolytic Polymerization on Hybrid Fluid Rubber (HF Rubber) for Smart Materials of Robotics.

Sensors (Basel, Switzerland)
The development of auditory sensors and systems is essential in smart materials of robotics and is placed at the strategic category of mutual communication between humans and robots. We designed prototypes of the rubber-made equilibrium and auditory ...

Synthetic growth by self-lubricated photopolymerization and extrusion inspired by plants and fungi.

Proceedings of the National Academy of Sciences of the United States of America
Many natural organisms, such as fungal hyphae and plant roots, grow at their tips, enabling the generation of complex bodies composed of natural materials as well as dexterous movement and exploration. Tip growth presents an exemplary process by whic...

Interpretable Machine Learning Models for Phase Prediction in Polymerization-Induced Self-Assembly.

Journal of chemical information and modeling
While polymerization-induced self-assembly (PISA) has become a preferred synthetic route toward amphiphilic block copolymer self-assemblies, predicting their phase behavior from experimental design is extremely challenging, requiring time and work-in...

Robot-Assisted Synthesis of Structure-Controlled Star-Cluster Hydrogels with Targeted Mechanophysical Properties for Biomedical Applications.

Biomacromolecules
Advancements in polymer chemistry have enabled the design of macromolecular structures with tailored properties for diverse applications. Reversible addition-fragmentation chain-transfer (RAFT) polymerization is a controlled technique for precise pol...

Design of Recyclable Plastics with Machine Learning and Genetic Algorithm.

Journal of chemical information and modeling
We present an artificial intelligence-guided approach to design durable and chemically recyclable ring-opening polymerization (ROP) class polymers. This approach employs a genetic algorithm (GA) that designs new monomers and then utilizes virtual for...